Examinando por Materia "Cadmium"
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Ítem Geospatial distribution of heavy metals in rice soils of northwestern Peru(Nature Portfolio (Springer Nature), 2025-08-21) Tarrillo Julca, Ever; Arce Inga, Marielita; Torres Herrera, Pedro Antonio; Tineo Flores, Daniel; Taboada Mitma, Victor Hugo; Cruz Luis, Juancarlos Alejandro; Rojas Briceño, Nilton B.; Atalaya Marin, Nilton; Gómez Fernández, Darwin; Goñas Goñas, MalluriThe presence of heavy metals in agricultural soils poses a threat to the development of sustainable agriculture and ensuring food security. The objective of this study was to evaluate the geospatial distribution of heavy metals in rice-growing soils within the Amojú River Basin, Jaen, Peru. Ninety-five soil samples were collected randomly, covering four altitudinal ranges, namely, very low (374–450 m above sea level (m a.s.l.)), low (450–571 m a.s.l.), medium (571–701 m a.s.l.) and high altitudes (701–1,034 m a.s.l.), and different agronomic management stages, including four phenological phases (seedling, tillering, filling and ripening) and two agricultural practices (resting and stubble burning). The evaluation was conducted via physicochemical analysis, the single-factor pollution index, and spatial interpolation techniques through the empirical Bayesian kriging (EBK) method. The results indicated that the contents of cadmium (Cd) and chromium (Cr) exceed the limits established in the Environmental Quality Standards (EQSs) for agricultural soils, with maximum Cd and Cr concentrations of 2 and 21 mg kg ⁻¹, respectively, mainly in very low-altitude areas (374–450 m a.s.l.). The single-factor pollution index results indicated slight Cd contamination and intense Cr contamination. Likewise, high levels of arsenic (As), Cd, and Cr were detected in soils managed via stubble burning, reaching 2, 2, and 16 mg kg ⁻¹, respectively. The highest Cr concentrations were located in the northeastern and western parts of the study area, whereas the highest Cd concentrations occurred in the northeastern and southwestern parts. These concentrations may be associated with potential contamination sources, with the use of phosphate fertilizers, water for cultivation, and soil erosion as key contributors. This study highlights the potential risk to rice productivity and crop safety, emphasizing the importance of implementing sustainable agricultural practices and monitoring strategies for heavy metals in soils associated with crops.Ítem Soil, site, and management factors affecting cadmium concentration in cacao-growing soils(MDPI, 2020-06-05) Scaccabarozzi, Daniela; Castillo, Luis; Aromatisi, Andrea; Milne, Lynne; Bullón Castillo, Adolfo Alejandro; Muñoz Rojas, MiriamSoil contamination by potentially toxic trace elements (PTEs) such as Cadmium (Cd), is a major environmental concern because of its potential implications to human health. Cacao-based products have been identified as food sources with relatively high Cd contents. Here, we assessed Cd concentrations of cacao-growing soils in four major agricultural regions with contrasting climates in Peru, one of the main exporters of cacao products worldwide. At each study site (n = 40) a broad range of potential factors affecting Cd concentration in soils, i.e., site, soil and management, were evaluated. Concentrations of Cd ranged between 1.1-3.2 mg kg-1. Mean values per region were below 2.7 mg kg-1, usually established as upper-limit for non-polluted soils. Cadmium concentrations were significantly (p < 0.001) higher in sites at higher elevations and in a temperate, drier climate. Cadmium correlated positively with pH (r = 0.57; p < 0.05) and was higher (p < 0.001) in alluvial sediments and Leptosols. Management factors (cacao variety, cultivation year, management practices) and agroecology did not affect Cd concentrations directly. Overall, this study highlights the importance of considering a broad range of both natural and anthropogenic factors to evaluate Cd concentrations in cacao-growing soils and contribute to effective and sustainable cacao production by improving land management and planning